Product ID:ETHER ANHYDROUS, 5499
MSDS Date:03/09/1992
FSC:6810
NIIN:00N054250
MSDS Number: BVWKT

J T BAKER INC

222 RED SCHOOL LANE
PHILLIPSBURG, NJ 08865
US

Emergency Phone: 908-859-2151;800-424-9300(CHEMTREC)

Info Phone: 800-582-2537

Cage: DO803

MALLINCKRODT BAKER, INC.

PHILLIPSBURG, NJ 08865 US

Telephone: 800-582-2537

Cage: 70829

ETHANE, 1,1'-OXYBIS-; (ETHYL ETHER) (DIETHYL ETHER) (SARA

CAS: 60-29-7

RTECS: KI5775000

Fraction By Weight: 97-100%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM;500 STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

(ORAL,RAT) 7060 MG/KG.

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: <2.5%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

DISCARD ANY REMAINING ETHER IN OPENED CNTNRS THAT IS

RTECS: 9999999ZZ

CAP. IMPORTANT - DO NOT USE AFTER EXPIRATION DATE.

RTECS: 9999999ZZ

HARMFUL IF SWALLOWED, INHALED/ABSORBED THRU SKIN.

RTECS: 9999999ZZ

AWAY FROM HEAT, SPARKS, FLAME. AVOID CONTACT W/EYES,

RTECS: 9999999ZZ

SMOKING. DO NOT EMPTY INTO DRAINS. TAKE PRECAUTIONARY

RTECS: 9999999ZZ

PROD, SECONDARY PROT CNTNRS MUST BE USED FOR

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:CNS DEPRESSION, HEADACHE,
NAUSEA, VOMITING, DROWSINESS, IRRITATION OF UPPER RESPIRATORY
TRACT, JAUNDICE, LIVER DAMAGE, UNCONSCIOUSNESS. SKIN
CONTACT:IRRITATION, PROLONGED CONTACT MAY CAUSE SENSIT. SKIN
ABSORPTION:RAPID ABSORPTION, CNS DEPRESSION, HEADACHE, NAUSEA,
VOMITING, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:DROWSINESS, JAUNDICE, LIVER DMG.
INGEST:CNS DEPRESS, HDCH, NAUS, VOMIT, DROW, NERVOUSNESS, JAUNDICE,
LIVER DMG, HEART FAILURE, RESP FAILURE, UNCON. CHRONIC:CNS DEPRESS.
TARGET ORGANS:CNS, EYE S, SKIN, MUC MEMBS, RESP SYS, LUNGS, HEART,
LIVER.
Medical Cond Aggravated by Exposure:NONE IDENTIFIED.

First Aid:INGEST:CALL MD. IF SWALLOWED, DO NOT INDUCE VOMITING. IF
CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. INHAL:REMOVE TO FRESH AIR.
IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GI VE OXYGEN. SKIN:IMMEDIATELY FLUSH W/PLENTY OF WATER
FOR AT LST 15 MINS WHILE REMOVING CONTAMINATED CLOTHING & SHOES.
WASH CLOTHING BEFORE RE-USE. EYE:IMMED FLUSH W/PLENTY OF WATER FOR
AT LST 15 MINS.

Flash Point Method:CC
Flash Point:-47F,-44C
Lower Limits:1.9%
Upper Limits:36%
Extinguishing Media:USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
(WATER MAY BE INEFFECTIVE.)
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
MOVE CNTNRS FROM FIRE AREA IF IT CAN BE DONE W/OUT RISK. USE WATER
TO KEEP FIRE-EXPOSED CNTNRS COOL.
Unusual Fire/Explosion Hazard:VAPS MAY FLOW ALONG SURFS TO DIST IGNIT
SOURCES & FLASH BACK. CLSD CNTNRS EXPOS TO HEAT MAY EXPLODE. CONT
W/STRONG OXIDIZERS MAY CAUSE FIRE. MAY FORM (SUPDAT)

Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG.
SHUT OFF IGNIT SOURCE; NO FLARES, SMOKING/FLAMES IN AREA. STOP LEAK
IF YOU CAN DO SO W/OUT RISK. USE H*2O SPRAY TO REDUCE VAP.TAKE UP
W/SAND/NON-COMBUST ABSORB MATL & PUT IN CNTNR FOR LATER
DISP.(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD. STORE IN
COOL, DRY, WELL-VENTILATED, FLAMM LIQ STOR AREA. ISOLATE FROM
INCOMPAT MATLS. AVOID BRTHG VAP. USE W/ADEQ VENT.
Other Precautions:BOND & GROUND CNTNRS WHEN TRANSFERRING LIQ. ETHER IS
SUBJECT TO PEROXIDE FORM IN OPENED CNTNRS & SHOULD BE PROT FROM
EXPOS TO AIR AS MUCH AS POSS. WHEN LOW PEROXIDE ETHER IS REQD, USE
ONLY MATL FROM U NOPENED CAN. DO NOT ALLOW TO (SUPDAT)

Respiratory Protection:RESPIRATORY PROTECTION IS REQUIRED IF AIRBORNE
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO 1000 PPM, A
NIOSH/MSHA APPRVD CHEM CARTRIDGE RESP W/ORGANIC VAP CARTRIDGE IS
REC. ABOVE THIS LEVEL, A NIOSH/MSHA APPRVD SCBA IS REC.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS. VENT HOOD.
Protective Gloves:NITRILE GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:UNIFORM, APRON ARE RECOMMENDED. LAB COAT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLO HAZ:EXPLO PEROXIDES, ESP WHEN HEATED & EXPOSED TO AIR . FORMS
SHOCK-SENSITIVE MIXTS W/CERTAIN OTHER MATLS. SPILL PROC: FLUSH AREA
W/WATER. J.T. BAKER SOLUSORB SOLV ABSORB IS REC FOR SPILLS OF THIS
PROD. OTHER PREC:EVAP TO NEAR DRYNESS. ADDN OF WATER/APPROP
REDUCING AGENTS WILL LESSEN PEROXIDE FORM. (ING 3)

Boiling Pt:B.P. Text:95.0F,35.0C
Melt/Freeze Pt:M.P/F.P Text:-177F,-116C
Vapor Pres:442 @ 20C
Vapor Density:2.6
Spec Gravity:0.71 (H*2O=1)
Evaporation Rate & Reference:37.5 (BUTYL ACETATE=1)
Solubility in Water:MODERATE (1-10%)
Appearance and Odor:CLEAR, COLORLESS LIQUID; CHARACTERISTIC ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG BASES, STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION,
LIGHT, AIR.
Hazardous Decomposition Products:EXPLOSIVE PEROXIDES, CARBON MONOXIDE,
CARBON DIOXIDE.

Waste Disposal Methods:DISPOSE I/A/W ALL APPLICABLE FEDERAL, STATE &
LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: U117
(TOXIC WASTE).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.